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Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive brilliant blue

Chengyuan SU,Weiguang LI,Xingzhe LIU,Xiaofei HUANG,Xiaodan YU

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 1,   Pages 37-45 doi: 10.1007/s11783-014-0729-y

Abstract: A study of the decolorization of reactive brilliant blue in an aqueous solution using Fe-Mn-sepiolite as a heterogeneous Fenton-like catalyst has been performed. The Fourier transform infrared (FTIR) spectra of the catalyst showed bending vibrations of the Fe-O. The X-ray diffraction (XRD) patterns of the catalyst showed characteristic diffraction peaks of α-Fe O , γ-Fe O and MnO. A four factor central composite design (CCD) coupled with response surface methodology (RSM) was applied to evaluate and optimize the important variables (catalyst addition, hydrogen peroxide dosage, initial pH value and initial dye concentration). When the reaction conditions were catalyst dosage= 0.4 g, [H O ]= 0.3 mL, pH= 2.5, [reactive brilliant blue] = 50 mg·L , and volume of solution= 500 mL at room temperature, the decolorization efficiency of reactive brilliant blue was 91.98% within 60 min. Moreover, the Fe-Mn-sepiolite catalyst had good stability for the degradation of reactive brilliant blue even after six cycles. Leaching of iron ions (<0.4 mg·L ) was observed. The decoloring process was reactive brilliant blue specific via a redox reaction. The benzene ring and naphthalene ring were first oxidized to open ring; these were then oxidized to the alcohol and carboxylic acid. The reactive brilliant blue was decomposed mainly by the attack of ·OH radicals including surface-bound ·OH radicals generated on the catalyst surface.

Keywords： Fe-Mn-sepiolite catalyst     heterogeneous Fenton-like     reactive brilliant blue     homogeneous precipitation    

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Effect of a less permeable stronger soil layer on the stability of non-homogeneous unsaturated slopes

Nabarun DEY, Aniruddha SENGUPTA

Frontiers of Structural and Civil Engineering 2020, Volume 14, Issue 6,   Pages 1462-1475 doi: 10.1007/s11709-020-0674-8

Abstract: It is observed that a less permeable, stronger silty sand layer in an otherwise homogeneous sandy soilNo shear band is found to initiate in a homogeneous sandy soil slope, whereas for a non-homogeneous slopeA discontinuity of the shear zone is also observed for the case of a non-homogeneous soil slope.The factor of safety of a non-homogeneous, unsaturated soil slope decreases because of the less permeable

Keywords： non-homogeneous slope     stronger soil layer     factor of safety     centrifuge model test     unsaturated soils    

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Control of homogeneous charge compression ignition combustion in a two-cylinder gasoline direct injection

WANG Zhi, WANG Jianxin, SHUAI Shijin, MA Qingjun, TIAN Guohong

Frontiers in Energy 2007, Volume 1, Issue 3,   Pages 311-315 doi: 10.1007/s11708-007-0045-3

Abstract: Homogeneous charge compression ignition (HCCI) has challenges in ignition timing control, combustion

Keywords： Homogeneous     control     combustion     consumption     extension    

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Liquid discharge plasma for fast biomass liquefaction at mild conditions: The effects of homogeneous

Sen Wang, Shiyun Liu, Danhua Mei, Rusen Zhou, Congcong Jiang, Xianhui Zhang, Zhi Fang, Kostya (Ken) Ostrikov

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 5,   Pages 763-771 doi: 10.1007/s11705-019-1896-y

Abstract: Different homogeneous catalysts are usually required for plasma-enabled biomass liquefaction to achieve

Keywords： discharge plasma     biomass liquefaction     catalyst     homogeneous catalysts    

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Modeling radiative effects of haze on summer-time convective precipitation over North China: a case study

Xuying WANG, Bin ZHANG

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 4, doi: 10.1007/s11783-016-0840-3

Abstract: We modeled the impact of haze radiative effects on precipitation in North China.Convection was the key factor that whether precipitation was enhanced or suppressed.Precipitation was often suppressed where CAPE, RH and updraft velocities were high.The convection was stronger over places with precipitation enhancement over 30 mm.water vapor to rise to a higher level and thus further suppressed precipitation.

Keywords： Haze     Aerosol radiative effects     Convective precipitation    

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Changes in hourly precipitation may explain the sharp reduction of discharge in the middle reach of the

Lin LUO, Zhongjing WANG

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 5,   Pages 756-768 doi: 10.1007/s11783-013-0563-7

Abstract: High temporal resolution precipitation (timescales between 1 and 4 h) data from the June to Septemberand significance of monotonic trends, and to find the change points in the mean and variance of the precipitationResults show that although the total amount of precipitation has slightly increased, the average rainfallThe study indicates that changes in hourly precipitation may be responsible for the sharp reduction of

Keywords： precipitation intensity     Mann-Kendall rank statistic     spatial and temporal distribution     climatic change    

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Effects of compression ratio on the combustion characteristics of a homogeneous charge compression ignition

SONG Ruizhi, ZHOU Longbao, LIU Shenghua, LI Wei, HU Tiegang

Frontiers in Energy 2007, Volume 1, Issue 4,   Pages 463-467 doi: 10.1007/s11708-007-0068-0

Abstract: The effects of homogeneous charge compression ignition (HCCI) engine compression ratio on its combustion

Keywords： homogeneous     cylinder     combustion     compression     dimethyl    

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Evaluation of precipitation behavior of zirconium molybdate hydrate

Liang ZHANG, Masayuki TAKEUCHI, Tsutomu KOIZUMI, Izumi HIRASAWA

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 1,   Pages 65-71 doi: 10.1007/s11705-013-1314-9

Abstract: In the dissolution step of spent nuclear fuel, there is a world-concern problem that zirconium molybdate hydrate precipitates as a byproduct, and accumulates in some reprocessing equipments. In order to prevent this accumulation, we have developed a new method based on the controlled reaction crystallization of zirconium molybdate hydrate (ZMH) in the reprocessing solution, followed by solid liquid separation. In order to measure the particle size of ZMH, batch crystallization experiments were conducted by varying nitric acid concentration and operating temperature. In result, almost all particle sizes scatter around 1 μm on average, despite the higher concentration of nitric aid and operating temperature, and then small particles grow up as an aggregate sticking to the crystallizer. Moreover, polymorph and color changing were observed by varying the concentration of nitric acid and reaction time. These results suggest that crystal color and adhesiveness are closely related to the particle size of ZMH. And the control of nitric acid concentration and small particle growth would be the useful technique to prevent the ZMH sticking.

Keywords： spent nuclear fuel     zirconium molybdate hydrate     cleaning method     accumulation    

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Reactive adsorption desulfurization over a Ni/ZnO adsorbent prepared by homogeneous precipitation

Aihua KONG, Yanyu WEI, Yonghong LI

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 2,   Pages 170-176 doi: 10.1007/s11705-013-1322-9

Abstract: A high-performance Ni/ZnO adsorbent was prepared by homogeneous precipitation using urea hydrolysis and

Keywords： nickel     reactive adsorption     desulfurization     thiophene    

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of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent extraction-precipitation

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 5,   Pages 902-912 doi: 10.1007/s11705-019-1887-z

Abstract: environmentally friendly method was developed to recover valuable metals by using a solvent extraction-precipitationFor the precipitation process, 91.05% of manganese was recovered as MnCO which meets the III grade standard

Keywords： high-manganese containing vanadium wastewater     solvent extraction     carbonate precipitation     vanadium titano-magnetite    

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LiFePO/C cathode materials synthesized by co-precipitation and microwave heating

XU Yunlong, TAO Lili, MA Hongyan, HUANG Huaqing

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 4,   Pages 422-427 doi: 10.1007/s11705-008-0082-4

Abstract: LiFePO/C cathode materials were synthesized by a combination of co-precipitation and microwave heating

Keywords： polyethylene     electrochemical performance     combination     co-precipitation     diffraction    

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CLIMATE-CHANGE-INDUCED TEMPORAL VARIATION IN PRECIPITATION INCREASES NITROGEN LOSSES FROM INTENSIVE CROPPING

Frontiers of Agricultural Science and Engineering 2022, Volume 9, Issue 3,   Pages 457-464 doi: 10.15302/J-FASE-2022452

Abstract: ListItem>

● A simple model was used to evaluate how increasing temporal variability in precipitation

Keywords： crop yield     fertilizer timing     nitrogen loss     precipitation variability     toy model    

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TRMM satellite onboard instruments and the application on precipitation analysis of their measurements

Fu Yunfei,Liu Qi,Wang Yu,Sun Liang,Li Rui,Ma Ming,Liu Guosheng

Strategic Study of CAE 2012, Volume 14, Issue 10,   Pages 43-50

Abstract: style="text-align: justify;">The method of satellite infrared and passive microwave remote sensing for precipitationAs for example, precipitation structure, relationship among altitude of cloud top and rain top with surfacerain rate for a summer hot convective precipitation system were brought forth together with analyzingof long time dataset of the TRMM precipitation radar on precipitation climatology in Asia.At last, theprospect of the satellite active and passive remote sensing of precipitation in the near future were

Keywords： TRMM     precipitation radar     microwave imager     spectrum     precipitation    

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EFFICIENT CONTAMINANT REMOVAL FROM LIQUID DIGESTATE OF PIG MANURE BY CHEMICAL PRECIPITATION AND CO MINERALIZATION

Frontiers of Agricultural Science and Engineering 2023, Volume 10, Issue 3,   Pages 479-491 doi: 10.15302/J-FASE-2023480

Abstract:

● LFD was treated by fly ash-based chemical precipitation and CO

Keywords： anaerobic digestion     chemical oxygen demand     fly ash     ion removal     total phosphate    

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Separation of 1,3-propanediol from glycerol-based fermentations of Klebsiella pneumoniae by alcohol precipitation

GAO Sujun, SUN Yaqin, XIU Zhilong

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 2,   Pages 202-207 doi: 10.1007/s11705-007-0037-1

Abstract: The influences of pH and water content in condensed broth on alcohol precipitation and dilution crystallizationThe experimen tal results indicated that alcohol precipitation and dilution crystallization was feasible
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Title Author Date Type Operation

Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive brilliant blue

Chengyuan SU,Weiguang LI,Xingzhe LIU,Xiaofei HUANG,Xiaodan YU

Journal Article

Effect of a less permeable stronger soil layer on the stability of non-homogeneous unsaturated slopes

Nabarun DEY, Aniruddha SENGUPTA

Journal Article

Control of homogeneous charge compression ignition combustion in a two-cylinder gasoline direct injection

WANG Zhi, WANG Jianxin, SHUAI Shijin, MA Qingjun, TIAN Guohong

Journal Article

Liquid discharge plasma for fast biomass liquefaction at mild conditions: The effects of homogeneous

Sen Wang, Shiyun Liu, Danhua Mei, Rusen Zhou, Congcong Jiang, Xianhui Zhang, Zhi Fang, Kostya (Ken) Ostrikov

Journal Article

Modeling radiative effects of haze on summer-time convective precipitation over North China: a case study

Xuying WANG, Bin ZHANG

Journal Article

Changes in hourly precipitation may explain the sharp reduction of discharge in the middle reach of the

Lin LUO, Zhongjing WANG

Journal Article

Effects of compression ratio on the combustion characteristics of a homogeneous charge compression ignition

SONG Ruizhi, ZHOU Longbao, LIU Shenghua, LI Wei, HU Tiegang

Journal Article

Evaluation of precipitation behavior of zirconium molybdate hydrate

Liang ZHANG, Masayuki TAKEUCHI, Tsutomu KOIZUMI, Izumi HIRASAWA

Journal Article

Reactive adsorption desulfurization over a Ni/ZnO adsorbent prepared by homogeneous precipitation

Aihua KONG, Yanyu WEI, Yonghong LI

Journal Article

of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent extraction-precipitation

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

Journal Article

LiFePO/C cathode materials synthesized by co-precipitation and microwave heating

XU Yunlong, TAO Lili, MA Hongyan, HUANG Huaqing

Journal Article

CLIMATE-CHANGE-INDUCED TEMPORAL VARIATION IN PRECIPITATION INCREASES NITROGEN LOSSES FROM INTENSIVE CROPPING

Journal Article

TRMM satellite onboard instruments and the application on precipitation analysis of their measurements

Fu Yunfei,Liu Qi,Wang Yu,Sun Liang,Li Rui,Ma Ming,Liu Guosheng

Journal Article

EFFICIENT CONTAMINANT REMOVAL FROM LIQUID DIGESTATE OF PIG MANURE BY CHEMICAL PRECIPITATION AND CO MINERALIZATION

Journal Article

Separation of 1,3-propanediol from glycerol-based fermentations of Klebsiella pneumoniae by alcohol precipitation

GAO Sujun, SUN Yaqin, XIU Zhilong

Journal Article